Deep xenoliths in alkalic porphyry, Liuhe, Yunnan, and implications to petrogenesis of alkalic porphyry and associated mineralizations   总被引：9，自引：0，他引：9  

Xianfan Liu  Xinzhi Zhan  Zhenmin Gao  Jiajun Liu  Chaoyang Li  Wenchao Su 《中国科学D辑(英文版)》1999,42(6):627-635

Na-rich microlite-glass is first discovered in deep-source xenoliths in alkali-rich porphyry, Liuhe village, Heqing County, Yunnan Province. It is shown that the ultramafic xenoliths originated from partial melting of primary mantle and the glass resulted from metasomatism between the xenoliths and mantle fluid derived from mantle degassing. Mantle metasomatism not only resulted in the enrichment of alkaline, large-ion elements, ore metals and volatiles but also created a favorable condition for the generation of alkaline magmas. The mantle xenoliths and their characteristics of mantle metasomatism provide important evidence for a better understanding of the petrogenesis and mineralization of the Cenozoic alkali-rich porphyry in western Yunnan.  相似文献   

珠江口表层水中主要常量离子的研究     

张力军  纪红  谢式南  陈国华  王渊 《中国海洋大学学报(自然科学版)》1998,(4)

９９４年９月采集了珠江口表层海水水样,并对其溶解态的Ｋ＋、Ｎａ＋、Ｃａ２＋、Ｍｇ２＋、ＳＯ２－４、Ｃｌ等化学要素进行了测定。结果表明,珠江口调查海域表层水中溶解态的Ｋ＋、Ｎａ＋、Ｃａ２＋、Ｍｇ２＋、ＳＯ２－４主要受陆源淡水与外海水物理混合稀释的影响,与Ｃｌ具有良好的直线正相关;Ｃａ２＋／Ｃｌ、ＳＯ２－４／Ｃｌ明显高于大洋水相应比值,Ｎａ＋／Ｃｌ、Ｍｇ２＋／Ｃｌ略高,而Ｋ＋／Ｃｌ比大洋比值低;在与中国其它各主要河口表层水对应Ｃｌ比较中,珠江口的ＳＯ２－４／Ｃｌ较高,而Ｃａ２＋／Ｃｌ,Ｍｇ２＋／Ｃｌ比值居低;上述各主要常量离子和Ｃｌ的等值线均沿自北向南走向递增。  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

Ancient deep roots for Mesozoic world-class gold deposits in the north China craton:An integrated genetic perspective     

Cheng-Xue Yang  M.Santosh 《地学前缘(英文版)》2020,11(1):203-214

The North China Craton(NCC)hosts some of the world-class gold deposits that formed more than 2 billion years after the major orogenic cycles and cratonization.The diverse models for the genesis of these deposits remain equivocal,and mostly focused on the craton margin examples,although synchronous deposits formed in the interior domains.Here we adopt an integrated geological and geophysical perspective to evaluate the possible factors that contributed to the formation of the major gold deposits in the NCC.In the Archean tectonic framework of the NCC,the locations of the major gold deposits fall within or adjacent to greenstone belts or the margins of micro-continents.In the Paleoproterozoic framework,they are markedly aligned along two major collisional sutures-the Trans North China Orogen and the Jiao-Liao-Ji Belt.Since the Mesozoic intrusions hosting these deposits do not carry adequate signals for the source of gold,we explore the deep roots based on available geophysical data.We show that the gold deposits are preferentially distributed above zones of uplifted MOHO and shallow LAB corresponding to thinned crust and eroded sub-lithospheric mantle,and that the mineralization is located above regions of high heat flow representing mantle upwelling.The NCC was at the center of a multi-convergent regime during the Mesozoic which intensely churned the mantle and significantly en riched it.The geophysical data on Moho and LAB upwarp from the centre towards east of the craton is more consistent with paleo-Pacific slab subduction from the east exerting the dominant control on lithospheric thinning.Based on these results,and together with an evaluation of the geochemical and isotopic features of the Mesozoic magmatic intrusions hosting the gold mineralization,we propose a genetic model that invokes reworking of ancient Au archives preserved in the lower crust and metasomatised upper mantle and which were generated through multiple subduction,underplating and cumulation events associated with cratonization of the NCC as well as the subduction-collision of Yangtze Craton with the NCC.The heat and material input along zones of heterogeneously thinned lithosphere from a rising turbulent mantle triggered by Mesozoic convergent margins surrounding the craton aided in reworking the deep roots of the ancient Au reservoirs,leading to the major gold metallogeny along craton margins as well as in the interior of the NCC.  相似文献   

九华山花岗岩体钠交代特征与成矿作用的初步探讨     

周家志 《铀矿地质》1991,7(6):328-334

本文分析和归纳了花岗岩、钠交代岩的产出条件、蚀变特征,论述了岩体中热液活动阶段划分及蚀变流体的演化。探讨了钠交代作用及其蚀变岩石对铍铀成矿所起的控制作用。  相似文献   

大义山西北端硼矿床特征及其控矿因素     

周荣文  唐先礼 《湖南地质》1990,9(3):20-24

湖南大义山西北端的硼矿属接触交代—热液叠加型。矿体赋存于大义山花岗岩体中上石炭统壶天群白云岩接触带中,呈层状、似层状,局部为透镜状,分枝复合明显。矿石组分复杂,结构构造多样。富镁的碳酸盐岩是有利的成矿围岩;富含硼、氟的大义山花岗岩体是成矿母岩;广泛发育的节理裂隙是容矿构造。外围尚有一定的找矿远景。  相似文献   

大兴安岭北段新林区塔木兰沟组火山岩成因及地幔富集作用     

杨华本  王文东  闫永生  魏小勇  耿成宝 《地质论评》2016,62(6):1471-1486

本文报道了大兴安岭北段新林区塔木兰沟组玄武岩样品锆石U-Pb定年结果和岩石地球化学分析,探讨了塔木兰沟组玄武岩的成因及中生代岩石圈地幔的性质。锆石U-Pb定年结果显示,塔木兰沟组玄武岩形成于晚侏罗世(~153Ma),该玄武岩样品的SiO_2含量介于49.96%~59.06%之间,全碱含量介于5.21%~7.44%之间,Mg~#{100×n(Mg~(2+))/[(n(Mg~(2+))+n(Fe~(2+))]}值介于50~94之间。该玄武岩相对富集轻稀土元素(LREEs)、亏损重稀土元素(HREEs),La_N/Yb_N值介于10.7~20.0之间,具有轻微的Eu异常(δEu=0.80~1.09),结合区域研究成果,认为塔木兰沟组玄武岩形成于蒙古—鄂霍茨克洋闭合造山后岩石圈伸展环境,源区岩浆起源于石榴子石相二辉橄榄岩与尖晶石相二辉橄榄岩部分熔融的混合形成,含富含挥发分的金云母和角闪石等,暗示岩石圈地幔经历了交代作用的改造,交代类型以俯冲板片流体/熔体交代为主。结合区域已有研究表明,本区地幔交代富集作用来源于蒙古—鄂霍茨克洋的向南俯冲,塔木兰沟组火山岩形成于蒙古~鄂霍茨克洋闭合造山后岩石圈伸展背景。  相似文献   

盐碱地中华绒螯蟹育苗水质调配技术的研究   总被引：2，自引：0，他引：2  

肖国强  潘鲁青  栾治华  王桓台  王国峰 《海洋科学》2003,27(12):1-4

研究了地下卤水中Na^ ／K^ 对中华绒螫蟹(Eriocheir sinensis)幼体生长发育的影响以及幼体对人工海水盐度的适应性。结果表明：随着地下卤水中Na^ ／K^ 的降低，中华绒螫蟹幼体存活率、变态率和体质量增长率逐渐升高，当地下卤水中的Na^ ／K^ 低于18、6时，中华绒螯蟹幼体的存活率、变态率和体质量增长率与海水对照相比差异不显著；人工海水盐度梯度设置为18～26，Z1→Z2、Z3→Z4、Z5→M各阶段不同处理组幼体存活率和体质量增长率差异显著，而变态率差异基本不显著，各阶段的最适盐度分别为20，22和20。  相似文献   

加拿大Slave 克拉通橄榄岩的平衡温压计算     

陈瑶  王勤 《高校地质学报》2022,28(4):457-472

加拿大Slave克拉通Jericho金伯利岩筒携带的橄榄岩包体提供了研究大陆岩石圈地幔物质组成和热结构的窗口。文章总结了地幔岩矿物温压计的研究进展,测量了Jericho金伯利岩携带的9个新鲜橄榄岩包体的矿物主量元素和微量元素,并使用不同的矿物温压计估算了平衡温度和压力。结果表明Nickel 和 Green（1985）的石榴子石—斜方辉石压力计可以较好地估算含石榴子石橄榄岩形成时的压力,Taylor（1998）二辉石温度计和Nimis 和 Taylor（2000）单斜辉石温度计的计算结果一致。具有粗粒变晶结构的尖晶石—石榴子石橄榄岩和石榴子石橄榄岩样品的平衡温度为575~843℃,压力为2.4~3.6 GPa,表明Slave克拉通岩石圈地幔温度较低。而残斑结构尖晶石—石榴子石二辉橄榄岩的平衡温度1109℃,压力为5.0 GPa,来源深度为~156 km,可能被早期金伯利岩浆携带到岩石圈地幔中部冷却,然后再被侏罗纪喷发的Jericho金伯利岩筒带到地表。使用石榴子石—单斜辉石稀土元素温压计获得的平衡温度高于主量元素温度计的结果,表明Slave克拉通岩石圈地幔经历了逐渐冷却的过程。此外,Slave克拉通浅部的尖晶石橄榄岩保留了强烈亏损的早期岩石圈地幔特征,而下部的岩石圈地幔经历了金伯利岩熔体和硅酸盐熔体的交代作用。  相似文献   

碳酸岩岩浆与地壳反应综述     

范朝熙  许成  崔莹  韦春婉  匡光喜  石爱国  李卓骐 《地学前缘》2022,29(4):330-344

碳酸岩是地表出露较少的地幔来源的岩石,其地幔交代作用已被广泛研究,而碳酸岩岩浆与地壳的反应过程却研究较少,目前已在中国草滩和丰镇地区、德国Kaiserstuhl地区、俄罗斯Petyayan-Vara地区和澳大利亚Nolans Bore矿床等各地被报道。碳酸岩岩浆与地壳反应的特征是可能形成大量富铁云母、辉石、榍石、钡冰长石等硅酸盐矿物并造成C-O和Sr-Nd同位素体系的扰动。实验岩石学研究发现碳酸岩岩浆在地幔与橄榄岩反应形成异剥橄榄岩,对应的在中下地壳反应形成反夕卡岩。碳酸岩岩浆与围岩的反应会造成局部Si的富集促使REE在早期岩浆阶段进入磷灰石,从而抑制稀土成矿。深部地壳的碳酸岩-硅酸岩反应在相同构造背景下通常不像浅部热液系统容易出露地表,并且其反应产物容易被误认为是夕卡岩矿物组合。因此,更多的高温高压实验研究以及对硅酸盐流体来源不是很清楚的高温夕卡岩矿物组合进行重新评估,将是揭示地壳深部反夕卡岩过程,特别是相关成矿作用的关键。  相似文献